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Charge Density and Polarising Power of Group 2 Metal Cations. Arrange sulphates of group in decreasing order of solubility of water. Hence polarising ability of the M2+ ion decreases down the group. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. The greater the charge density the easier it is for the cation to hydrate and hence dissolve in water due to greater attraction with the polar water molecules. Beryllium carbonate decomposing most easily. | EduRev NEET Question is disucussed on EduRev Study Group … MgCO3(s ) MgO(s) + CO2(g ) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. The solubility of carbonates increases down the group in alkali metals (except ) . For Alkaline Earth metals Group 2. Let's use MgCO 3 as an example. The size of the sulphate ion is larger compared to the Group 2 cations. How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? Apart from being the largest NEET community, EduRev has the largest solved The larger compounds further down require more heat than the lighter compounds in order to decompose. The relative decomposition temperatures are: MnSO4 755, FeSO4 537, CoSO4 708, NiSO4 675, CuSO4 598, ZnSO4 646, CdSO4 816, PbSO4 803, MgSO4 895, CaSO4 1149, and SrSO4 1374°C. Thanks for viewing. This is clearly seen if we observe the reactions of magnesium and calcium in water. charge density), there is significant difference in terms of their ability to hydrate. MgSO 4 Soluble. This is affected by the radius of the cation, which is more able to polarise the anion when the cation is small and highly charged. The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. The carbonates become more stable to heat as you go down the Group. All the enthalpy definitions including Lattice Enthalpy, Enthalpy of Hydration and Enthalpy of solutions. a) Virtually no reaction occurs between magnesium and cold water. As the size of the Group 2 cations increases down the group, the difference between the size of the metal cations and the size of the SO 4 2-ions decreases. All of these carbonates are white solids, and the oxides that are produced are also white solids. The sulphates of alkaline earth metals are all white solids. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. Small highly charged positive ions distort the electron cloud of the anion. However, in a reaction with steam it forms magnesium oxide and hydrogen. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. But carbonates of alkaline earth metals are insoluble in water. More the strong bonding more thermal stability. This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. Magnesium sulphate dissolves in water whereas barium sulphate does not. So what causes this trend? Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. However, due to the change in ionic radius (i.e. The thermal stability increases down the group for sulphates of alkaline earth metals. b) Calcium is more reactive. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. If you add sodium sulphate or sulphuric acid to an aqueous solution containing calcium, strontium or barium ions a white precipitate forms:. Reactivity increases down the group. In this video we want to explain the trends that we observe for thermal decomposition temperatures for Group 2 Metal Salts. As we move down the group 2 the size of cations increases and sulphate is a big ion group according to its size. The larger the anion the easier the distortion, as seen with the carbonate ion. Thermal decomposition of Group 2 nitrates has a similar pattern, decompose to form nitrogen dioxide, oxygen and the oxide: Order of stability: 6 | P a g e h t t p s : / / w w w . This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements – beryllium, magnesium, calcium, strontium and barium. Solubility of Hydroxides and Flourides INCREASES from top to bottom. Mg(s) + H2O(g) → MgO(s) + H2(g) b) Calcium is more reactive. But group-2 carbonates are soluble in a solution of CO 2 due to formation of HCO 3-. Alkali metal sulphates are more soluble in water than alkaline earth metals. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. over here on EduRev! Answers of How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO3(s ) CaO(s) + CO2(g ) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. The reason, once more, is that the polarising power of the M2+ decreases as ionic radius increases. are solved by group of students and teacher of NEET, which is also the largest student Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. 3.2k VIEWS. 2.0k VIEWS. solubility: sulphates of alkali metals are soluble in water. All these carbonates decompose on heating to give CO 2 and metal oxide. The solubility of these sulphates decreases as we descend the group, with barium sulphate being insoluble in water. Ionisation energy decreases due to extra shielding from inner shells and increase in distance from the nucleus. Thermal decomposition is the term given to splitting up a compound by heating it. Nitrates of group -1 and group-2 metals are all soluble in water. The solubility of the Group 2 sulphates decreases down the group. However, sulphates of alkaline earth metals show varied trends. Sulphates of alkali metals are soluble in water. FAQs on Appendix - … Less attractions are formed with water molecules. The relative decomposition temperatures are: MnSO 4 755, FeSO 4 537, CoSO 4 708, NiSO 4 675, CuSO 4 598, ZnSO 4 646, CdSO 4 816, PbSO 4 803, MgSO 4 895, CaSO 4 1149, and SrSO 4 1374°C. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Decreasing order of solubility of group in decreasing order of solubility of the anion bank for NEET this. Produce an alkaline solution of CO 2 due to the metal oxide and carbon dioxide gas the cloud... It is elements increases down the group 2 carbonates and nitrates of group -1 and group-2 metals are white! And increase in ease at losing two outer electrons as we move down the group ) Ca... 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